On Saturday,FIFAsuspended Rubiales while its disciplinary committee investigates his conduct at the Womens World Cup final.
Hermoso has said she did not consent to the kiss, which came during the teams on-field celebration.
The teams players have said they will not play any more games as long as Rubiales is in charge.
President of the Royal Spanish Football Federation Luis Rubiales (R) kisses Jennifer Hermoso of Spain (L) during the medal ceremonyNoemi Llamas/Eurasia Sport Images/Getty Images
The league filed one of several official complaints against Rubiales that Spains government received in the past week.
Luis Rubiales is finished.
He has dug his own grave with his acts and his words, Alvarez said.
FIFA has given no timetable for a ruling.
The bodys disciplinary judges can impose sanctions ranging from warnings and fines to suspensions from the sport.
Local media originally reported that Rubiales would announce his resignation to Fridays general assembly of the federation.
Hermoso responded that Rubiales was lying about the kiss being consensual and that she had felt intimidated.
